编译 | 未玖
Nature,做作周论 27 July 2023, VOL 619, ISSUE 7971
《做作》2023年7月27日 ,第619卷,出书7971期
地舆学Astronomy
Spectroscopic identification of water emission from a main-belt comet
主带彗星水辐射的文导光谱识别
▲ 作者:Michael S. P. Kelley, Henry H. Hsieh, Dennis Bodewits, Moha妹妹ad Saki, Geronimo L. Villanueva, Stefanie N. Milam, et al.
▲ 链接:
https://www.nature.com/articles/s41586-023-06152-y
▲ 摘要 :
主带彗星是位于小行星带的小型太阳系天体,在其克日点通道中一再展现出相似彗星的做作周论行动(即灰尘彗发或者彗尾) ,强烈表明冰升华。出书尽管主带彗星的文导存在象征着小行星带中有尚存的水冰,但尽管用天下上最大的做作周论望远镜妨碍了详尽探测,在这些天体周围仍未发现气体 。出书
钻研组揭示了詹姆斯·韦伯太空望远镜的文导审核服从 ,它清晰地表明,做作周论主带彗星238P/Read有一个水蒸气彗发,出书但缺少清晰的文导二氧化碳气体彗发 。该发现表明 ,做作周论Read彗星的出书行动是由水冰升华驱动的 ,这象征着主带彗星与艰深彗星群有着根基的文导差距。
不论Read彗星是否履历了差距的组成情景或者演化史,它都不太可能是最近才从外太阳系突入小行星带的。凭证这些服从 ,主带彗星彷佛代表了一种挥发性物资样本,且这种物资当初在典型彗星的审核以及陨石记实中不代表性,这对于清晰早期太阳系的挥发性物资及其随后演化颇为紧张。
▲ Abstract:
Main-belt comets are small Solar System bodies located in the asteroid belt that repeatedly exhibit comet-like activity (that is, dust comae or tails) during their perihelion passages, strongly indicating ice sublimation. Although the existence of main-belt comets implies the presence of extant water ice in the asteroid belt, no gas has been detected around these objects despite intense scrutiny with the world’s largest telescopes. Here we present James Webb Space Telescope observations that clearly show that main-belt comet 238P/Read has a coma of water vapour, but lacks a significant CO2 gas coma. Our findings demonstrate that the activity of comet Read is driven by water–ice sublimation, and implies that main-belt comets are fundamentally different from the general cometary population. Whether or not comet Read experienced different formation circumstances or evolutionary history, it is unlikely to be a recent asteroid belt interloper from the outer Solar System. On the basis of these results, main-belt comets appear to represent a sample of volatile material that is currently unrepresented in observations of classical comets and the meteoritic record, making them important for understanding the early Solar System’s volatile inventory and its subsequent evolution.
物理学Physics
Femtosecond proton transfer in urea solutions probed by X-ray spectroscopy
X射线光谱学探测尿素溶液中的飞秒质子转移
▲ 作者:Zhong Yin, Yi-Ping Chang, Tadas Bal?iūnas, Yashoj Shakya, Aleksa Djorovi?, Geoffrey Gaulier, et al.
▲ 链接:
https://www.nature.com/articles/s41586-023-06182-6
▲ 摘要 :
质子转移是水相化学中最根基的使命之一 ,也是超快电子以及妄想能源学耦合的典型典型 。在飞秒光阴尺度上解耦电子以及核能源学仍是一项难题挑战 ,特意是在液相 、生化历程的做作情景中 。
钻研组运用台式水窗X射线罗致光谱的配合特色来揭示水溶液中离子化尿素二聚体的飞秒质子转移能源学。借助于重新算量子力学以及份子力学合计 ,运用X射线罗致光谱的元素特异性以及位点抉择性 ,钻研组揭示了除了质子转移之外 ,尿素二聚体的后续重排以及电子妄想相关变更若何经由位点抉择性来识别。
这些服从表明 ,平板射流 、台式X射线罗致光谱在剖析生物份子零星中溶液相超快能源学方面具备至关大的后劲。
▲ Abstract:
Proton transfer is one of the most fundamental events in aqueous-phase chemistry and an emblematic case of coupled ultrafast electronic and structural dynamics. Disentangling electronic and nuclear dynamics on the femtosecond timescales remains a formidable challenge, especially in the liquid phase, the natural environment of biochemical processes. Here we exploit the unique features of table-top water-window X-ray absorption spectroscopy to reveal femtosecond proton-transfer dynamics in ionized urea dimers in aqueous solution. Harnessing the element specificity and the site selectivity of X-ray absorption spectroscopy with the aid of ab initio quantum-mechanical and molecular-mechanics calculations, we show how, in addition to the proton transfer, the subsequent rearrangement of the urea dimer and the associated change of the electronic structure can be identified with site selectivity. These results establish the considerable potential of flat-jet, table-top X-ray absorption spectroscopy in elucidating solution-phase ultrafast dynamics in biomolecular systems.
能源迷信Energy Science
Accelerating the energy transition towards photovoltaic and wind in China
减速中国向光伏大风能的能源转型
▲ 作者 :Yijing Wang, Rong Wang, Katsumasa Tanaka, Philippe Ciais, Josep Penuelas, Yves Balkanski, et al.
▲ 链接:
https://www.nature.com/articles/s41586-023-06180-8
▲ 摘要:
中国到2060年实现碳中以及目的要求将光伏(PV)大风能的发电量从1 PWh/年削减至10~15 PWh/年。可是 ,凭证可再沉闷力配置装备部署装置的历史速率,即最近的高分说率能源零星模子以及基于中国“十四五”能源睁开(CFED)的预料,到2060年 ,发电量仅能抵达5~9.5 PWh/年 。
钻研组表明